The photoelectric effect is a result of electron-photon pair collisions.
“[Planck’s] derivation was of unparalleled boldness, but found brilliant confirmation. … However, it remained unsatisfactory that the [classical mechanical] analysis, which led to [Planck’s Radiation Law], is incompatible with quantum theory, and it is not surprising that Planck himself and all theoreticians who work on this topic incessantly tried to modify the theory such as to base it on noncontradictory foundations.” –Einstein
The Problem with Schrödinger’s Wave Equation
The biggest question still plaguing Schrödinger’s wave equation was the role of the wavefunction. Sure, mathematically it’s clear: it’s the solution to Schrödinger’s wave equation and the “all-powerful function” as a result. However, physically it was still a big mystery to everyone, including Schrödinger himself.
With his work in 1916-7, Einstein was able to arrive at a “much more” quantum derivation of Planck’s Radiation Law. However, in the end he fell short, having to rely on assumptions. In 1924, Satyendra Nath Bose provided the first “fully” quantum derivation of Planck’s radiation law, which revealed the deeper nature of light that had eluded everyone else, including Einstein. With this work, he created the new area of physics known as quantum statistics.
In 1905, a young Albert Einstein wrote a paper (while working as a patent clerk) on a well-known physical phenomenon of the time, Brownian motion, which had first been noted in 1827. Einstein’s theory correctly described Brownian motion, and at the heart of his theory was the existence of atoms that were in constant motion.
Einstein Revisits His Theory of Light
By 1911, Einstein had already hypothesized that light consists of particles he called light quanta (later called photons). Moreover, he had shown that light has an inherent quality, whereby it exhibits both wave and particle properties. Although, he had seen further than anyone into the mysterious nature of light, it continued to perplex him:
“I do not ask anymore whether these [light] quanta really exist. Nor do I attempt any longer to construct them, since I now know my brain is incapable of advancing in that direction.”
In 1921, Einstein won the Nobel Prize. The citation reads:
“To Albert Einstein for his services to theoretical physics and especially for his discovery of the law of the photoelectric effect.”
To be sure, Einstein is being acknowledge for the “the law of the photoelectric effect”, in other words for his photoelectric equation, but not for the photon concept. This attitude would persist until 1923, when new experimental results would convert pretty much everyone to the existence of photons.
In 1923, Arthur Compton’s (1892-1962) light scattering experiments provided further support for Einstein’s hypothesis for the particle nature of light.
The atoms of a Bose-Einstein fluid are in the exact same quantum state.
In 1905, Einstein established wave-particle duality for light. In 1923, de Broglie extended it to all quantum particles. In an interview in 1963 de Broglie reflected on his epiphany:
“As in my conversations with my brother we always arrived at the conclusion that in the case of X-rays one had both waves and [particles], thus suddenly – … it was certain in the course of summer 1923 – I got the idea that one had to extend this duality to material particles, especially to electrons.”
In 1925, Einstein predicted a very unusual phase transition that occurs for the quantum ideal gas. Einstein describes the phenomenon in a letter to Paul Ehrenfest (1880–1933):
“From a certain temperature on, the molecules ‘condense’ without attractive forces, that is, they accumulate at zero velocity.”
In other words, as the temperature is lowered, the atoms in the gas begin to “pile up” or condense into the lowest (single particle) energy state, which is the one with zero kinetic energy; there’s a critical temperature whereby a phase transition (now called (Bose-Einstein condensation) occurs. This effect becomes most pronounced as the temperature is lowered to absolute zero, at which point, all the gas atoms condense into this lowest energy state. This phenomenon is an example of quantum entanglement.
After 1925, Einstein turned his back forever on quantum mechanics, arguing that its probabilistic nature was a fundamental flaw.
If in 1917 Einstein truly saw the probabilistic nature as a shortcoming, later he would be less forgiving.
A long time proponent of atoms, Boltzmann died unaware of Einstein’s landmark 1905 paper, which proved their existence.
Einstein’s 1905 paper, On a Heuristic Point of View Concerning the Production and Transformation of Light is often (wrongly) referred to as his paper on the photoelectric effect.
In his1905 paper, On a Heuristic Point of View Concerning the Production and Transformation of Light, Einstein showed how his newly introduced light quanta hypothesis could be used to interpret several well-known experimental observations, the most notable of these phenomena being the photoelectric effect.
The major theme of Einstein’s 1905 paper, On a Heuristic Point of View Concerning the Production and Transformation of Light, was that light (under certain circumstances) behaves as if it’s comprised of individual particles rather than waves. These particles, or “chunks” of light were originally called light quanta, and then later came to be called photons.
It was the first of Einstein’s 1905 papers, On a Heuristic Point of View Concerning the Production and Transformation of Light, which he referred to as “very revolutionary” – the only time he would ever say this about any of his work, in fact – and which, in part would win him the Nobel Prize in 1921.